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  1. Abstract The Sun sporadically produces eruptive events leading to intense fluxes of solar energetic particles (SEPs) that dramatically disrupt the near-Earth radiation environment. Such events have been directly studied for the last decades but little is known about the occurrence and magnitude of rare, extreme SEP events. Presently, a few events that produced measurable signals in cosmogenic radionuclides such as 14 C, 10 Be and 36 Cl have been found. Analyzing annual 14 C concentrations in tree-rings from Switzerland, Germany, Ireland, Russia, and the USA we discovered two spikes in atmospheric 14 C occurring in 7176 and 5259 BCE. The ~2% increases of atmospheric 14 C recorded for both events exceed all previously known 14 C peaks but after correction for the geomagnetic field, they are comparable to the largest event of this type discovered so far at 775 CE. These strong events serve as accurate time markers for the synchronization with floating tree-ring and ice core records and provide critical information on the previous occurrence of extreme solar events which may threaten modern infrastructure. 
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    Abstract. The last glacial period is characterized by a number of millennial climateevents that have been identified in both Greenland and Antarctic ice coresand that are abrupt in Greenland climate records. The mechanisms governingthis climate variability remain a puzzle that requires a precisesynchronization of ice cores from the two hemispheres to be resolved.Previously, Greenland and Antarctic ice cores have been synchronizedprimarily via their common records of gas concentrations or isotopes fromthe trapped air and via cosmogenic isotopes measured on the ice. In thiswork, we apply ice core volcanic proxies and annual layer counting toidentify large volcanic eruptions that have left a signature in bothGreenland and Antarctica. Generally, no tephra is associated with thoseeruptions in the ice cores, so the source of the eruptions cannot beidentified. Instead, we identify and match sequences of volcanic eruptionswith bipolar distribution of sulfate, i.e. unique patterns of volcanicevents separated by the same number of years at the two poles. Using thisapproach, we pinpoint 82 large bipolar volcanic eruptions throughout thesecond half of the last glacial period (12–60 ka). Thisimproved ice core synchronization is applied to determine the bipolarphasing of abrupt climate change events at decadal-scale precision. Inresponse to Greenland abrupt climatic transitions, we find a response in theAntarctic water isotope signals (δ18O and deuterium excess)that is both more immediate and more abrupt than that found with previousgas-based interpolar synchronizations, providing additional support for ourvolcanic framework. On average, the Antarctic bipolar seesaw climateresponse lags the midpoint of Greenland abrupt δ18O transitionsby 122±24 years. The time difference between Antarctic signals indeuterium excess and δ18O, which likewise informs the timeneeded to propagate the signal as described by the theory of the bipolarseesaw but is less sensitive to synchronization errors, suggests anAntarctic δ18O lag behind Greenland of 152±37 years.These estimates are shorter than the 200 years suggested by earliergas-based synchronizations. As before, we find variations in the timing andduration between the response at different sites and for different eventssuggesting an interaction of oceanic and atmospheric teleconnection patternsas well as internal climate variability. 
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  3. Abstract. During the last glacial period Northern Hemisphere climate was characterizedby extreme and abrupt climate changes, so-called Dansgaard–Oeschger (DO)events. Most clearly observed as temperature changes in Greenland ice-corerecords, their climatic imprint was geographically widespread. However, thetemporal relation between DO events in Greenland and other regions isuncertain due to the chronological uncertainties of each archive, limitingour ability to test hypotheses of synchronous change. In contrast, theassumption of direct synchrony of climate changes forms the basis of manytimescales. Here, we use cosmogenic radionuclides (10Be,36Cl, 14C) to link Greenland ice-core records toU∕Th-dated speleothems, quantify offsets between the two timescales, andimprove their absolute dating back to 45000 years ago. This approach allowsus to test the assumption that DO events occurred synchronously betweenGreenland ice-core and tropical speleothem records with unprecedentedprecision. We find that the onset of DO events occurs within synchronizationuncertainties in all investigated records. Importantly, we demonstrate thatlocal discrepancies remain in the temporal development of rapid climatechange for specific events and speleothems. These may either be related tothe location of proxy records relative to the shifting atmospheric fronts orto underestimated U∕Th dating uncertainties. Our study thus highlightsthe potential for misleading interpretations of the Earth system whenapplying the common practice of climate wiggle matching.

     
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  4. ABSTRACT Radiocarbon (14C) ages cannot provide absolutely dated chronologies for archaeological or paleoenvironmental studies directly but must be converted to calendar age equivalents using a calibration curve compensating for fluctuations in atmospheric 14C concentration. Although calibration curves are constructed from independently dated archives, they invariably require revision as new data become available and our understanding of the Earth system improves. In this volume the international 14C calibration curves for both the Northern and Southern Hemispheres, as well as for the ocean surface layer, have been updated to include a wealth of new data and extended to 55,000 cal BP. Based on tree rings, IntCal20 now extends as a fully atmospheric record to ca. 13,900 cal BP. For the older part of the timescale, IntCal20 comprises statistically integrated evidence from floating tree-ring chronologies, lacustrine and marine sediments, speleothems, and corals. We utilized improved evaluation of the timescales and location variable 14C offsets from the atmosphere (reservoir age, dead carbon fraction) for each dataset. New statistical methods have refined the structure of the calibration curves while maintaining a robust treatment of uncertainties in the 14C ages, the calendar ages and other corrections. The inclusion of modeled marine reservoir ages derived from a three-dimensional ocean circulation model has allowed us to apply more appropriate reservoir corrections to the marine 14C data rather than the previous use of constant regional offsets from the atmosphere. Here we provide an overview of the new and revised datasets and the associated methods used for the construction of the IntCal20 curve and explore potential regional offsets for tree-ring data. We discuss the main differences with respect to the previous calibration curve, IntCal13, and some of the implications for archaeology and geosciences ranging from the recent past to the time of the extinction of the Neanderthals. 
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